Description
تفصیل
Uranium (yew-ray-nee-am) is a silvery -white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. The uranium nucleus binds between 141 and 146 neutrons, establishing six isotopes (U-233 through U-238), the most common of which are uranium-238 (146 neutrons) and uranium-235 (143 neutrons). All isotopes are unstable and uranium is weakly radioactive. Uranium has the second highest atomic weight of the naturally occurring elements, lighter only than plutonium-244.Its density is about 70% higher than that of lead, but not as dense as gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.
In nature, uranium is found as uranium-238 (99.2742%), uranium-235 (0.7204%), and a very small amount of uranium-234 (0.0054%). Uranium decays slowly by emitting an alpha particle. The half-life of uranium-238 is about 4.47 billion years and that of uranium-235 is 704 million years,making them useful in dating the age of the Earth.
Many contemporary uses of uranium exploit its unique nuclear properties. Uranium-235 has the distinction of being the only naturally occurring fissile isotope. Uranium-238 is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is also important in nuclear technology. While uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons, uranium-235 and to a lesser degree uranium-233 have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors, and produces the fissile material for nuclear weapons. Depleted uranium (238U) is used in kinetic energy penetrators and armor plating.
Uranium is used as a colorant in uranium glass, producing orange-red to lemon yellow hues. It was also used for tinting and shading in early photography. The 1789 discovery of uranium in the mineral pitchblende is credited to Martin Heinrich Klaproth, who named the new element after the planet Uranus. Eugène- Melchior Péligot was the first person to isolate the metal and its radioactive properties were discovered in 1896 by Antoine Becquerel. Research by Enrico Fermi and others starting in 1934 led to its use as a fuel in the nuclear power industry and in Little Boy, the first nuclear weapon used in war. An ensuing arms race during the Cold War between the United States and the Soviet Union produced tens of thousands of nuclear weapons that used uranium metal and uranium-derived plutonium-239.The security of those weapons and their fissile material following the breakup of the Soviet Union in 1991 is an ongoing concern for public health and safety.See Nuclear proliferation.
Uranium-235 was the first isotope that was found to be fissile. Other naturally occurring isotopes are fissionable, but not fissile. Upon bombardment with slow neutrons, its uranium-235 isotope will most of the time divide into two smaller nuclei, releasing nuclear binding energy and more neutrons. If too many of these neutrons are absorbed by other uranium-235 nuclei, a nuclear chain reaction occurs that results in a burst of heat or (in special circumstances) an explosion. In a nuclear reactor, such a chain reaction is slowed and controlled by a neutron poison, absorbing some of the free neutrons. Such neutron absorbent materials are often part of reactor control rods (see nuclear reactor physics for a description of this process of reactor control).
As little as 15 lb (7 kg) of uranium-235 can be used to make an atomic bomb.The first nuclear bomb used in war, Little Boy, relied on uranium fission, while the very first nuclear explosive (The gadget) and the bomb that destroyed Nagasaki (Fat Man) were plutonium bombs.
Uranium metal has three allotropic forms:
a (orthorhombic) stable up to 660 °C
ß (tetragonal) stable from 660 °C to 760 °C
r (body-centered cubic) from 760 °C to melting point—this is the most malleable and ductile state.
In 1972 French physicist Francis Perrin discovered fifteen ancient and no longer active natural nuclear fission reactors in three separate ore deposits at the Oklo mine in Gabon, West Africa, collectively known as the Oklo Fossil Reactors. The ore deposit is 1.7 billion years old; then, uranium-235 constituted about three percent of the total uranium on Earth.This is high enough to permit a sustained nuclear fission chain reaction to occur, provided other supporting conditions exist.
The discovery of the element is credited to the German chemist Martin Heinrich Klaproth. While he was working in his experimental laboratory in Berlin in 1789, Klaproth was able to precipitate a yellow compound (likely sodium diuranate) by dissolving pitchblende in nitric acid and neutralizing the solution with sodium hydroxide.Klaproth assumed the yellow substance was the oxide of a yet-undiscovered element and heated it with charcoal to obtain a black powder, which he thought was the newly discovered metal itself (in fact, that powder was an oxide of uranium).He named the newly discovered element after the planet Uranus, which had been discovered eight years earlier by William Herschel (who had named the planet after the primordial Greek god of the sky).
In 1841, Eugène-Melchior Péligot, Professor of Analytical Chemistry at the Conservatoire National des Arts et Métiers (Central School of Arts and Manufactures) in Paris, isolated the first sample of uranium metal by heating uranium tetrachloride with potassium.Uranium was not seen as being particularly dangerous during much of the 19th century, leading to the development of various uses for the element. One such use for the oxide was the aforementioned but no longer secret coloring of pottery and glass.
Antoine Henri Becquerel discovered radioactivity by using uranium in 1896. Becquerel made the discovery in Paris by leaving a sample of a uranium salt, K2UO2 (SO4)2, on top of an unexposed photographic plate in a drawer and noting that the plate had become 'fogged'.He determined that a form of invisible light or rays emitted by uranium had exposed the plate.
On 2 December 1942, as part of the Manhattan Project, another team led by Enrico Fermi was able to initiate the first artificial self-sustained nuclear chain reaction, Chicago Pile-1. Working in a lab below the stands of Stagg Field at the University of Chicago, the team created the conditions needed for such a reaction by piling together 400 tons (360 tonnes) of graphite, 58 tons (53 tonnes) of uranium oxide, and six tons (five and a half tonnes) of uranium metal.
Two major types of atomic bombs were developed by the United States during World War II: a uranium-based device (codenamed "Little Boy") whose fissile material was highly enriched uranium, and a plutonium-based device whose plutonium was derived from uranium-238. The uranium-based Little Boy device became the first nuclear weapon used in war when it was detonated over the Japanese city of Hiroshima on 6 August 1945.
Uranium is a naturally occurring element that can be found in low levels within all rock, soil, and water. Uranium is also the highest-numbered element to be found naturally in significant quantities on earth and is always found combined with other element.
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